Images surfaced online of Sebastian Stan (via CBM), where apparently Bucky seems to be in Romania in the movie as the newspapers behind Bucky seem to indicate.
The earlier report also mentioned Chris Evans and Anthony Mackie are in town to shoot scenes for Captain America: Civil War along with Daniel Bruhl, who is playing Baron Zemo.
“Captain America: Civil War” has a May 6, 2016 release date directed by Anthony and Joe Russo starring Chris Evans, Robert Downey Jr., Scarlett Johansson, Jeremy Renner, Elizabeth Olsen, Sebastian Stan, Anthony Mackie, Frank Grillo, Paul Bettany, Don Cheadle, Emily VanCamp, William Hurt, Martin Freeman and Chadwick Boseman as Black Panther.
Captain America: Civil War picks up where Avengers: Age of Ultron left off, as Steve Rogers leads the new team of Avengers in their continued efforts to safeguard humanity. After another international incident involving the Avengers results in collateral damage, political pressure mounts to install a system of accountability and a governing body to determine when to enlist the services of the team. The new status quo fractures the Avengers while they try to protect the world from a new and nefarious villain.